KMS Qingdao Institute of Biomass Energy and Bioprocess Technology ,CAS
| Investigation on the effect of Nb doping on the oxidation mechanism of Ti3SiC2 | |
| Zhenga, Lili1,2,3; Hua, Qingsong1,2; Li, Xichao3,4; Li, Meishuan3; Qian, Yuhai3; Xu, Jingjun3; Zhang, Jianmin1,2; Zheng, Zongmin1,2; Dai, Zuoqiang1,2; Zhang, Hongxin1,2; Zhang, Tiezhu1,2 | |
| 2018-08-01 | |
| Source Publication | CORROSION SCIENCE
 |
| ISSN | 0010-938X |
| Volume | 140Pages:374-378 |
| Abstract | Nb doping substantially changes the oxidation mechanism and significantly enhances its oxidation resistance of Ti3SiC2 at 800 degrees C. After Nb doping, the oxidation of Ti3SiC2 is only controlled by the inward diffusion of O, while the outward diffusion of Ti is restrained totally. The oxide layer structure changes from a duplex-layer of TiO2 outer layer and TiO2+SiO2 mixture inner layer to a single TiO2+SiO2 mixture layer. It is proposed that Nb doping decreases the concentrations of oxygen vacancies and Ti interstitials in the formed TiO2, leading to the completely restrained outward diffusion of Ti and the decreased oxidation rate. |
| Keyword | Ti3SiC2Nb doping Oxidation mechanism Ion diffusion Defect concentration |
| DOI | 10.1016/j.corsci.2018.05.028 |
| WOS Keyword | HIGH-TEMPERATURE OXIDATION ; 1100 DEGREES-C ; SEMICONDUCTING PROPERTIES ; TITANIUM-DIOXIDE ; DEFECT CHEMISTRY ; BEHAVIOR ; AIR ; COMPOSITES ; TI3ALC2 ; AL |
| Language | 英语 |
| Funding Project | National Science Foundation of China[51271191] ; National Science Foundation of China[51571205] ; National Key Research and Development Program of China[2017YFB0102004] ; Shandong Province Key Research and Development Program[2017CXGC0502] ; Qingdao postdoctoral research project ; Scientific Research Start-up Fund of Qingdao University[41117010089] |
| WOS Research Area | Materials Science ; Metallurgy & Metallurgical Engineering |
| Funding Organization | National Science Foundation of China ; National Key Research and Development Program of China ; Shandong Province Key Research and Development Program ; Qingdao postdoctoral research project ; Scientific Research Start-up Fund of Qingdao University |
| WOS Subject | Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering |
| WOS ID | WOS:000440121100036 |
| Publisher | PERGAMON-ELSEVIER SCIENCE LTD |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.qibebt.ac.cn/handle/337004/12371 |
| Collection | 中国科学院青岛生物能源与过程研究所 |
| Corresponding Author | Zhenga, Lili; Li, Xichao |
| Affiliation | 1.Qingdao Univ, Natl Engn Res Ctr Intelligent Elect Vehicle Power, 308 Ningxia Rd, Qingdao 266071, Peoples R China 2.Qingdao Univ, Coll Mech & Elect Engn, 308 Ningxia Rd, Qingdao 266071, Peoples R China 3.Chinese Acad Sci, Inst Met Res, Shenyang Natl Lab Mat Sci, Shenyang 110016, Liaoning, Peoples R China 4.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China |
| Recommended Citation GB/T 7714 | Zhenga, Lili,Hua, Qingsong,Li, Xichao,et al. Investigation on the effect of Nb doping on the oxidation mechanism of Ti3SiC2[J]. CORROSION SCIENCE,2018,140:374-378. |
| APA | Zhenga, Lili.,Hua, Qingsong.,Li, Xichao.,Li, Meishuan.,Qian, Yuhai.,...&Zhang, Tiezhu.(2018).Investigation on the effect of Nb doping on the oxidation mechanism of Ti3SiC2.CORROSION SCIENCE,140,374-378. |
| MLA | Zhenga, Lili,et al."Investigation on the effect of Nb doping on the oxidation mechanism of Ti3SiC2".CORROSION SCIENCE 140(2018):374-378. |
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