Nitrogen Production by Efficiently Removing Oxygen From Air Using a Perovskite Hollow-Fiber Membrane With Porous Catalytic Layer

doi:10.3389/fchem.2018.00329

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	Nitrogen Production by Efficiently Removing Oxygen From Air Using a Perovskite Hollow-Fiber Membrane With Porous Catalytic Layer
	Hu, Tianmiao 1,2; Zhou, Hangyue 1,2; Peng, Hui1 ; Jiang, Heqing1
	2018-08-06
发表期刊	FRONTIERS IN CHEMISTRY
ISSN	2296-2646
卷号	6 页码:7
摘要	Nowadays, nitrogen is mainly produced from air by cryogenic separation, pressureswing adsorption (PSA) and polymeric membrane technology. In this paper, we report a perovskite membrane-based nitrogen production route, which is basically driven by methane combustion. By coupling air separation with methane combustion on the opposite sides of oxygen-permeable perovskite membrane, most of oxygen in air is efficiently removed through the perovskite membrane and then consumed by methane oxidation. A nitrogen production rate of ca. 23 cm(3) min(-1) with purity of 98-99% was successfully achieved, and remained stable over 120 h, with a methane conversion of 71-73% on the other side of perovskite membrane. This work demonstrates that the joint use of oxygen-permeable perovskite membrane and methane oxidation is a promising strategy for nitrogen production and inspires more research efforts in the field of gas separation.
关键词	nitrogen production perovskite oxygen transport membrane hollow-fiber catalytic layer
DOI	10.3389/fchem.2018.00329
关键词[WOS]	GAS SEPARATION ; SELECTIVE MEMBRANES ; PARTIAL OXIDATION ; REACTOR ; PERMEATION ; HYDROGEN ; ETHYLENE ; STRATEGY ; METHANE ; OXIDE
语种	英语
资助项目	National Natural Science Foundation of China[21471156] ; National Natural Science Foundation of China[51761145107]
WOS研究方向	Chemistry
项目资助者	National Natural Science Foundation of China
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000440786500001
出版者	FRONTIERS MEDIA SA
引用统计
文献类型	期刊论文
条目标识符	http://ir.qibebt.ac.cn/handle/337004/12344
专题	中国科学院青岛生物能源与过程研究所
通讯作者	Peng, Hui; Jiang, Heqing
作者单位	1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao Key Lab Funct Membrane Mat & Membrane Tec, Qingdao, Peoples R China 2.Univ Chinese Acad Sci, Beijing, Peoples R China
推荐引用方式 GB/T 7714	Hu, Tianmiao,Zhou, Hangyue,Peng, Hui,et al. Nitrogen Production by Efficiently Removing Oxygen From Air Using a Perovskite Hollow-Fiber Membrane With Porous Catalytic Layer[J]. FRONTIERS IN CHEMISTRY,2018,6:7.
APA	Hu, Tianmiao,Zhou, Hangyue,Peng, Hui,&Jiang, Heqing.(2018).Nitrogen Production by Efficiently Removing Oxygen From Air Using a Perovskite Hollow-Fiber Membrane With Porous Catalytic Layer.FRONTIERS IN CHEMISTRY,6,7.
MLA	Hu, Tianmiao,et al."Nitrogen Production by Efficiently Removing Oxygen From Air Using a Perovskite Hollow-Fiber Membrane With Porous Catalytic Layer".FRONTIERS IN CHEMISTRY 6(2018):7.