| Conversion of fructose into 5-hydroxymethylfurfural (HMF) and its derivatives promoted by inorganic salt in alcohol | |
Liu, Jitian1,2; Tang, Yu1,3; Wu, Kaigui2; Bi, Caifeng2; Cui, Qiu1
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| 2012-03-01 | |
| 发表期刊 | CARBOHYDRATE RESEARCH
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| 卷号 | 350期号:1页码:20-24 |
| 摘要 | The conversion of d-fructose to 5-hydroxymethylfurfural (HMF) on a 1 mmol scale was achieved in good yield (68%) using NH4Cl as catalyst in isopropanol at 120 °C. About 3% of 5-i-propoxymethylfurfural was formed. The reaction in ethanol at 100 °C on a 10 g scale gave a total yield of HMF and 5-ethoxymethylfurfural of 42%. No mineral acid such as H2SO4 and HCl are required.; The conversion of D-fructose to 5-hydroxymethylfurfural (HMF) on a 1 mmol scale was achieved in good yield (68%) using NH4Cl as catalyst in isopropanol at 120 degrees C. About 3% of 5-i-propoxymethylfurfural was formed. The reaction in ethanol at 100 degrees C on a 10 g scale gave a total yield of HMF and 5-ethoxymethylfurfural of 42%. No mineral acid such as H2SO4 and HCl are required. (C) 2012 Elsevier Ltd. All rights reserved. |
| 文章类型 | Article |
| 关键词 | Fructose Hmf Emf Inorganic Salt Alcohol |
| 学科领域 | 代谢物组学 |
| WOS标题词 | Science & Technology ; Life Sciences & Biomedicine ; Physical Sciences |
| DOI | 10.1016/j.carres.2011.12.006 |
| 关键词[WOS] | IONIC LIQUIDS ; SELECTIVE DEHYDRATION ; CATALYZED CONVERSION ; SOLID ACID ; BIOMASS ; GLUCOSE ; EFFICIENT ; FUELS ; HYDROGENATION ; SUGARS |
| 收录类别 | SCI ; CCR |
| 语种 | 英语 |
| WOS研究方向 | Biochemistry & Molecular Biology ; Chemistry |
| WOS类目 | Biochemistry & Molecular Biology ; Chemistry, Applied ; Chemistry, Organic |
| WOS记录号 | WOS:000301127400003 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.qibebt.ac.cn/handle/337004/1226 |
| 专题 | 代谢物组学研究组 |
| 作者单位 | 1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Key Lab Energy Genet, Qingdao 266101, Peoples R China 2.Ocean Univ China, Coll Chem & Chem Engn, Qingdao 266101, Peoples R China 3.Tianjin Univ, Sch Pharmaceut Sci & Technol, Tianjin Key Lab Modern Drug Delivery & High Effic, Tianjin 300072, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Jitian,Tang, Yu,Wu, Kaigui,et al. Conversion of fructose into 5-hydroxymethylfurfural (HMF) and its derivatives promoted by inorganic salt in alcohol[J]. CARBOHYDRATE RESEARCH,2012,350(1):20-24. |
| APA | Liu, Jitian,Tang, Yu,Wu, Kaigui,Bi, Caifeng,&Cui, Qiu.(2012).Conversion of fructose into 5-hydroxymethylfurfural (HMF) and its derivatives promoted by inorganic salt in alcohol.CARBOHYDRATE RESEARCH,350(1),20-24. |
| MLA | Liu, Jitian,et al."Conversion of fructose into 5-hydroxymethylfurfural (HMF) and its derivatives promoted by inorganic salt in alcohol".CARBOHYDRATE RESEARCH 350.1(2012):20-24. |
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