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Manganese monoxide/titanium nitride composite as high performance anode material for rechargeable Li-ion batteries
Xu, Gaojie1,2; Zhang, Lixue1; Guo, Chaowei3; Gu, Lin4; Wang, Xiaogang1; Han, Pengxian1; Zhang, Kejun1; Zhang, Chuanjian1; Cui, Guanglei1
2012-12-15
发表期刊ELECTROCHIMICA ACTA
卷号85期号:1页码:345-351
摘要To develop new anode materials for Li-ion batteries, manganese monoxide/titanium nitride (MnO/TiN) composite was prepared by a facile nitridation procedure. Through the analysis of XRD, TEM, EDS and XPS data, it is found that MnO is homogenously mixed with TiN. Due to that TiN in the composite offers a conducting network and acts as a barrier to effectively buffer the volume expansion/contraction of MnO during the Li+ insertion/extraction process, the MnO/TiN electrode exhibits superior lithium storage properties than pristine MnO electrode. As a result, the Li-ion battery with MnO/TiN composite as anode displays a high and reversible specific capacity of 656 mAh g−1 after the 140th cycle at 200 mA g−1, and it still delivers a capacity of 210 mAh g−1 at 2 A g−1.; To develop new anode materials for Li-ion batteries, manganese monoxide/titanium nitride (MnO/TiN) composite was prepared by a facile nitridation procedure. Through the analysis of XRD, TEM, EDS and XPS data, it is found that MnO is homogenously mixed with TIN. Due to that TiN in the composite offers a conducting network and acts as a barrier to effectively buffer the volume expansion/contraction of MnO during the Li+ insertion/extraction process, the MnO/TiN electrode exhibits superior lithium storage properties than pristine MnO electrode. As a result, the Li-ion battery with MnO/TiN composite as anode displays a high and reversible specific capacity of 656 mAh g(-1) after the 140th cycle at 200 mAg(-1), and it still delivers a capacity of 210 mAh g(-1) at 2 A g(-1). (C) 2012 Elsevier Ltd. All rights reserved.
文章类型Article
关键词Mno/tin Composite Lithium Storage Anode Li-ion Batteries
学科领域仿生能源系统
WOS标题词Science & Technology ; Physical Sciences
DOI10.1016/j.electacta.2012.08.091
关键词[WOS]THIN-FILM ANODE ; HIGH-CAPACITY ; VANADIUM NITRIDE ; LITHIUM STORAGE ; HYBRID MATERIAL ; ELECTRODE MATERIALS ; OXIDE ; NANOCOMPOSITES ; NANOPARTICLES ; GRAPHENE
收录类别SCI
语种英语
WOS研究方向Electrochemistry
WOS类目Electrochemistry
WOS记录号WOS:000314376000049
引用统计
被引频次:27[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.qibebt.ac.cn/handle/337004/1164
专题仿生与固态能源系统研究组
作者单位1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China
2.Ocean Univ China, Coll Chem & Chem Engn, Qingdao 266100, Peoples R China
3.Xi An Jiao Tong Univ, Sch Mat Sci & Engn, Xian 710049, Peoples R China
4.Chinese Acad Sci, Inst Phys, Beijing 100080, Peoples R China
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Xu, Gaojie,Zhang, Lixue,Guo, Chaowei,et al. Manganese monoxide/titanium nitride composite as high performance anode material for rechargeable Li-ion batteries[J]. ELECTROCHIMICA ACTA,2012,85(1):345-351.
APA Xu, Gaojie.,Zhang, Lixue.,Guo, Chaowei.,Gu, Lin.,Wang, Xiaogang.,...&Cui, Guanglei.(2012).Manganese monoxide/titanium nitride composite as high performance anode material for rechargeable Li-ion batteries.ELECTROCHIMICA ACTA,85(1),345-351.
MLA Xu, Gaojie,et al."Manganese monoxide/titanium nitride composite as high performance anode material for rechargeable Li-ion batteries".ELECTROCHIMICA ACTA 85.1(2012):345-351.
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