Manganese monoxide/titanium nitride composite as high performance anode material for rechargeable Li-ion batteries | |
Xu, Gaojie1,2; Zhang, Lixue1; Guo, Chaowei3; Gu, Lin4; Wang, Xiaogang1; Han, Pengxian1; Zhang, Kejun1; Zhang, Chuanjian1; Cui, Guanglei1 | |
2012-12-15 | |
发表期刊 | ELECTROCHIMICA ACTA |
卷号 | 85期号:1页码:345-351 |
摘要 | To develop new anode materials for Li-ion batteries, manganese monoxide/titanium nitride (MnO/TiN) composite was prepared by a facile nitridation procedure. Through the analysis of XRD, TEM, EDS and XPS data, it is found that MnO is homogenously mixed with TiN. Due to that TiN in the composite offers a conducting network and acts as a barrier to effectively buffer the volume expansion/contraction of MnO during the Li+ insertion/extraction process, the MnO/TiN electrode exhibits superior lithium storage properties than pristine MnO electrode. As a result, the Li-ion battery with MnO/TiN composite as anode displays a high and reversible specific capacity of 656 mAh g−1 after the 140th cycle at 200 mA g−1, and it still delivers a capacity of 210 mAh g−1 at 2 A g−1.; To develop new anode materials for Li-ion batteries, manganese monoxide/titanium nitride (MnO/TiN) composite was prepared by a facile nitridation procedure. Through the analysis of XRD, TEM, EDS and XPS data, it is found that MnO is homogenously mixed with TIN. Due to that TiN in the composite offers a conducting network and acts as a barrier to effectively buffer the volume expansion/contraction of MnO during the Li+ insertion/extraction process, the MnO/TiN electrode exhibits superior lithium storage properties than pristine MnO electrode. As a result, the Li-ion battery with MnO/TiN composite as anode displays a high and reversible specific capacity of 656 mAh g(-1) after the 140th cycle at 200 mAg(-1), and it still delivers a capacity of 210 mAh g(-1) at 2 A g(-1). (C) 2012 Elsevier Ltd. All rights reserved. |
文章类型 | Article |
关键词 | Mno/tin Composite Lithium Storage Anode Li-ion Batteries |
学科领域 | 仿生能源系统 |
WOS标题词 | Science & Technology ; Physical Sciences |
DOI | 10.1016/j.electacta.2012.08.091 |
关键词[WOS] | THIN-FILM ANODE ; HIGH-CAPACITY ; VANADIUM NITRIDE ; LITHIUM STORAGE ; HYBRID MATERIAL ; ELECTRODE MATERIALS ; OXIDE ; NANOCOMPOSITES ; NANOPARTICLES ; GRAPHENE |
收录类别 | SCI |
语种 | 英语 |
WOS研究方向 | Electrochemistry |
WOS类目 | Electrochemistry |
WOS记录号 | WOS:000314376000049 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.qibebt.ac.cn/handle/337004/1164 |
专题 | 仿生与固态能源系统研究组 |
作者单位 | 1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China 2.Ocean Univ China, Coll Chem & Chem Engn, Qingdao 266100, Peoples R China 3.Xi An Jiao Tong Univ, Sch Mat Sci & Engn, Xian 710049, Peoples R China 4.Chinese Acad Sci, Inst Phys, Beijing 100080, Peoples R China |
推荐引用方式 GB/T 7714 | Xu, Gaojie,Zhang, Lixue,Guo, Chaowei,et al. Manganese monoxide/titanium nitride composite as high performance anode material for rechargeable Li-ion batteries[J]. ELECTROCHIMICA ACTA,2012,85(1):345-351. |
APA | Xu, Gaojie.,Zhang, Lixue.,Guo, Chaowei.,Gu, Lin.,Wang, Xiaogang.,...&Cui, Guanglei.(2012).Manganese monoxide/titanium nitride composite as high performance anode material for rechargeable Li-ion batteries.ELECTROCHIMICA ACTA,85(1),345-351. |
MLA | Xu, Gaojie,et al."Manganese monoxide/titanium nitride composite as high performance anode material for rechargeable Li-ion batteries".ELECTROCHIMICA ACTA 85.1(2012):345-351. |
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