KMS Qingdao Institute of Biomass Energy and Bioprocess Technology ,CAS
| Electric-Field-Directed Parallel Alignment Architecting 3D Lithium-Ion Pathways within Solid Composite Electrolyte | |
Liu, Xueqing1,2; Peng, Sha1,2; Gao, Shuyu1; Cao, Yuancheng1; You, Qingliang2; Zhou, Liyong2; Jin, Yongcheng3 ; Liu, Zhihong1; Liu, Jiyan1,2
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| 2018-05-09 | |
| Source Publication | ACS APPLIED MATERIALS & INTERFACES
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| ISSN | 1944-8244 |
| Volume | 10Issue:18Pages:15691-15696 |
| Abstract | It is of great significance to seek high-performance solid electrolytes via a facile chemistry and simple process for meeting the requirements of solid batteries. Previous reports revealed that ion conducting pathways within ceramic-polymer composite electrolytes mainly occur at ceramic particles and the ceramic-polymer interface. Herein, one facile strategy toward ceramic particles' alignment and assembly induced by an external alternating-current (AC) electric field is presented. It was manifested by an in situ optical microscope that Li1.3Al0.3Ti1.7(PO4)(3) particles and poly(ethylene glycol) diacrylate in poly(dimethylsiloxane) (LATP@PEGDA@PDMS) assembled into three-dimensional connected networks on applying an external AC electric field. Scanning electron microscopy revealed that the ceramic LATP particles aligned into a necklacelike assembly. Electrochemical impedance spectroscopy confirmed that the ionic conductivity of this necklacelike alignment was significantly enhanced compared to that of the random one. It was demonstrated that this facile strategy of applying an AC electric field can be a very effective approach for architecting three-dimensional lithium-ion conductive networks within solid composite electrolyte. |
| Subtype | Article |
| Keyword | Solid Composite Electrolyte Electric Field Ceramic Particles Alignment Ionic Conductivity |
| WOS Headings | Science & Technology ; Technology |
| DOI | 10.1021/acsami.8b01631 |
| WOS Keyword | POLYMER ELECTROLYTES ; POLYETHYLENE OXIDE ; BATTERIES ; CONDUCTIVITY ; NANOPARTICLES ; TRANSPORT ; ENHANCEMENT ; FILMS ; GLASS |
| Indexed By | SCI |
| Language | 英语 |
| WOS Research Area | Science & Technology - Other Topics ; Materials Science |
| Funding Organization | National Key Research and Development (R&D) Program of China(2016YFB0401505) ; "Chutian Scholar Program" of Hubei province |
| WOS Subject | Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary |
| WOS ID | WOS:000432205800041 |
| Publisher | AMER CHEMICAL SOC |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.qibebt.ac.cn/handle/337004/11406 |
| Collection | 中国科学院青岛生物能源与过程研究所 |
| Corresponding Author | Liu, Zhihong; Liu, Jiyan |
| Affiliation | 1.Jianghan Univ, Minist Educ, Key Lab Optoelect Chem Mat & Devices, Wuhan 430056, Hubei, Peoples R China 2.Jianghan Univ, Flexible Display Mat & Technol Coinnovat Ctr Hube, Wuhan 430056, Hubei, Peoples R China 3.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China |
| Recommended Citation GB/T 7714 | Liu, Xueqing,Peng, Sha,Gao, Shuyu,et al. Electric-Field-Directed Parallel Alignment Architecting 3D Lithium-Ion Pathways within Solid Composite Electrolyte[J]. ACS APPLIED MATERIALS & INTERFACES,2018,10(18):15691-15696. |
| APA | Liu, Xueqing.,Peng, Sha.,Gao, Shuyu.,Cao, Yuancheng.,You, Qingliang.,...&Liu, Jiyan.(2018).Electric-Field-Directed Parallel Alignment Architecting 3D Lithium-Ion Pathways within Solid Composite Electrolyte.ACS APPLIED MATERIALS & INTERFACES,10(18),15691-15696. |
| MLA | Liu, Xueqing,et al."Electric-Field-Directed Parallel Alignment Architecting 3D Lithium-Ion Pathways within Solid Composite Electrolyte".ACS APPLIED MATERIALS & INTERFACES 10.18(2018):15691-15696. |
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