An NNN-Pincer-Cobalt Complex Catalyzed Highly Markovnikov-Selective Alkyne Hydrosilylation

doi:10.1021/acs.orglett.8b02746

QIBEBT-IR

	An NNN-Pincer-Cobalt Complex Catalyzed Highly Markovnikov-Selective Alkyne Hydrosilylation
	Zhang, Shaochun 1; Ibrahim, Jessica Juweriah 1,2; Yang, Yong 1
	2018-10-05
发表期刊	ORGANIC LETTERS
ISSN	1523-7060
卷号	20 期号:19 页码:6265-6269
摘要	A new NNN pincer (amine-pyridine-imine, API) cobalt complex, which is bench-stable and is applicable for the highly efficient and regioselective hydrosilylation of terminal alkynes, is developed. A broad set of alpha-vinylsilanes was successfully synthesized in good to high yields with up to 98/2 Markovnikov regioselectivity. This protocol can be readily scaled up for gram-scale synthesis and demonstrates the most efficient cobalt-catalyzed hydrosilylation of alkynes with turnover frequencies as high as 126 720 h(-1) to date.
DOI	10.1021/acs.orglett.8b02746
关键词[WOS]	N-HETEROCYCLIC CARBENES ; SILICON-CONTAINING COMPOUNDS ; O-DONOR LIGAND ; TERMINAL ALKYNES ; RHODIUM(I) COMPLEXES ; RUTHENIUM COMPLEXES ; NICKEL-COMPLEXES ; IRIDIUM CATALYST ; METAL-COMPLEXES ; TRANS ADDITION
语种	英语
资助项目	13th-Five Key Project of the Chinese Academy of Sciences[Y7720519KL] ; QIBEBT
WOS研究方向	Chemistry
项目资助者	13th-Five Key Project of the Chinese Academy of Sciences ; QIBEBT
WOS类目	Chemistry, Organic
WOS记录号	WOS:000447118200061
出版者	AMER CHEMICAL SOC
引用统计
文献类型	期刊论文
条目标识符	http://ir.qibebt.ac.cn/handle/337004/11339
专题	中国科学院青岛生物能源与过程研究所
通讯作者	Yang, Yong
作者单位	1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, CAS Key Lab Biobased Mat, Qingdao 266101, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式 GB/T 7714	Zhang, Shaochun,Ibrahim, Jessica Juweriah,Yang, Yong. An NNN-Pincer-Cobalt Complex Catalyzed Highly Markovnikov-Selective Alkyne Hydrosilylation[J]. ORGANIC LETTERS,2018,20(19):6265-6269.
APA	Zhang, Shaochun,Ibrahim, Jessica Juweriah,&Yang, Yong.(2018).An NNN-Pincer-Cobalt Complex Catalyzed Highly Markovnikov-Selective Alkyne Hydrosilylation.ORGANIC LETTERS,20(19),6265-6269.
MLA	Zhang, Shaochun,et al."An NNN-Pincer-Cobalt Complex Catalyzed Highly Markovnikov-Selective Alkyne Hydrosilylation".ORGANIC LETTERS 20.19(2018):6265-6269.