KMS Qingdao Institute of Biomass Energy and Bioprocess Technology ,CAS
| Fluoride graphdiyne as a free-standing electrode displaying ultra-stable and extraordinary high Li storage performance | |
| He, Jianjiang1; Wang, Ning1; Yang, Ze1; Shen, Xiangyan1; Wang, Kun1; Huang, Changshui1; Yi, Yuanping2; Tu, Zeyi2; Li, Yuliang2 | |
| 2018-10-01 | |
| Source Publication | ENERGY & ENVIRONMENTAL SCIENCE
 |
| ISSN | 1754-5692 |
| Volume | 11Issue:10Pages:2893-2903 |
| Abstract | In natural two-dimensional (2D) materials (such as graphene, transition metal dichalcogenides and transition metal carbides), energy and power density are inevitably hindered by Li ion diffusion perpendicular to the compact atomic layer. At the same time, their cycling stability is affected by side reactions due to the large specific surface area and high activity of surface atoms. Here we report the preparation of a new 2D carbon rich framework called fluoride graphdiyne (F-GDY). The experiments, together with theoretical calculations, show that extraordinarily high reversible capacity (1700 mA h g(-1)) and extremely stable cycle performance (9000 cycles) are achieved by the reversible transition between C-F semi-ionic bonds and ionic bonds at the plateaus of 0.9 V. This bottom-up strategy offers a versatile approach to the rational design of ultra-stable flexible 2D materials through solution-based processability for application in the efficient electrodes of high performance rechargeable batteries. |
| DOI | 10.1039/c8ee01642a |
| WOS Keyword | LITHIUM-ION BATTERIES ; METAL-ORGANIC FRAMEWORKS ; ENERGY-STORAGE ; 2-DIMENSIONAL NANOMATERIALS ; COUPLING REACTION ; CARBON-BLACKS ; GRAPHENE ; CONVERSION ; CONSTRUCTION ; COMPOSITES |
| Language | 英语 |
| Funding Project | National Natural Science Foundation of China[21790051] ; National Natural Science Foundation of China[21771187] ; National Natural Science Foundation of China[21790050] ; Hundred Talents Program of the Chinese Academy of Sciences ; Frontier Science Research Project of the Chinese Academy of Sciences[QYZDB-SSW-JSC052] ; Natural Science Foundation of Shandong Province (China) for Distinguished Young Scholars[JQ201610] |
| WOS Research Area | Chemistry ; Energy & Fuels ; Engineering ; Environmental Sciences & Ecology |
| Funding Organization | National Natural Science Foundation of China ; Hundred Talents Program of the Chinese Academy of Sciences ; Frontier Science Research Project of the Chinese Academy of Sciences ; Natural Science Foundation of Shandong Province (China) for Distinguished Young Scholars |
| WOS Subject | Chemistry, Multidisciplinary ; Energy & Fuels ; Engineering, Chemical ; Environmental Sciences |
| WOS ID | WOS:000448339100013 |
| Publisher | ROYAL SOC CHEMISTRY |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.qibebt.ac.cn/handle/337004/11190 |
| Collection | 中国科学院青岛生物能源与过程研究所 |
| Corresponding Author | Huang, Changshui; Li, Yuliang |
| Affiliation | 1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, 189 Songling Rd, Qingdao 266101, Peoples R China 2.Chinese Acad Sci, Inst Chem, CAS Key Lab Organ Solids, BNLMS, Beijing 100190, Peoples R China |
| Recommended Citation GB/T 7714 | He, Jianjiang,Wang, Ning,Yang, Ze,et al. Fluoride graphdiyne as a free-standing electrode displaying ultra-stable and extraordinary high Li storage performance[J]. ENERGY & ENVIRONMENTAL SCIENCE,2018,11(10):2893-2903. |
| APA | He, Jianjiang.,Wang, Ning.,Yang, Ze.,Shen, Xiangyan.,Wang, Kun.,...&Li, Yuliang.(2018).Fluoride graphdiyne as a free-standing electrode displaying ultra-stable and extraordinary high Li storage performance.ENERGY & ENVIRONMENTAL SCIENCE,11(10),2893-2903. |
| MLA | He, Jianjiang,et al."Fluoride graphdiyne as a free-standing electrode displaying ultra-stable and extraordinary high Li storage performance".ENERGY & ENVIRONMENTAL SCIENCE 11.10(2018):2893-2903. |
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