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Transformation/degradation of tetrabromobisphenol A and its derivatives: A review of the metabolism and metabolites
Liu, Aifeng1; Zhao, Zongshan1; Qu, Guangbo2; Shen, Zhaoshuang1; Shi, Jianbo2,3; Jiang, Guibin2
2018-12-01
发表期刊ENVIRONMENTAL POLLUTION
ISSN0269-7491
卷号243页码:1141-1153
摘要Although the abiotic and biotic transformation/degradation (T/D) processes of tetrabromobisphenol A (TBBPA) have been widely investigated in model experiments, few reviews have focused on these processes along with their metabolites or degradation products. In this paper, we summarize the current knowledge on the T/D of TBBPA and its derivatives, including abiotic and biotic T/D strategies/conditions, mechanisms, metabolites and environmental occurrences. Various treatments, such as pyrolysis, photolysis, chemical reactions and biotransformation, have been employed to study the metabolic mechanism of TBBPA and its derivatives and to remediate associated contaminated environments. To date, more than 100 degradation products and metabolites have been identified, dominated by less brominated compounds such as bisphenol A, 2,6-dibromo-4-isopropylphenol, 2,6-dibromo-4-hydroxylphenol, 2,6-dibromophenol, isopropylene-2,6-dibromophenol, 4-(2-hydroxyisopropyl)-2,6-dibromophenol, etc. It can be concluded that the T/D of TBBPA mainly takes place through debromination and beta-scission. In some environmental media and human and animal tissues, brominated metabolites, glucoside and sulfate derivatives are also important T/D products. Here, the T/D products of TBBPA and its derivatives have been most comprehensively presented from the literature in recent 20 years. This review will enhance the understanding of the environmental behaviors of TBBPA-associated brominated flame retardants along with their ecological and health risks. (C) 2018 Elsevier Ltd. All rights reserved.
关键词TBBPA TBBPA derivatives Degradation Transformation Decomposition
DOI10.1016/j.envpol.2018.09.068
关键词[WOS]BROMINATED FLAME RETARDANTS ; POLYBROMINATED DIPHENYL ETHERS ; PRINTED-CIRCUIT BOARDS ; JAPANESE BREAST-MILK ; BISPHENOL-A ; THERMAL-DEGRADATION ; RIVER SEDIMENT ; PHOTOCATALYTIC DEGRADATION ; REDUCTIVE DEHALOGENATION ; ANAEROBIC DEGRADATION
语种英语
资助项目National Natural Science Foundation of China[21707148] ; National Natural Science Foundation of China[21527901] ; China Postdoctoral Science Foundation[2018T110715] ; China Postdoctoral Science Foundation[2016M602210]
WOS研究方向Environmental Sciences & Ecology
项目资助者National Natural Science Foundation of China ; China Postdoctoral Science Foundation
WOS类目Environmental Sciences
WOS记录号WOS:000449892700039
出版者ELSEVIER SCI LTD
引用统计
文献类型期刊论文
条目标识符http://ir.qibebt.ac.cn/handle/337004/11047
专题中国科学院青岛生物能源与过程研究所
通讯作者Zhao, Zongshan
作者单位1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, CAS Key Lab Biobased Mat, Qingdao 266101, Peoples R China
2.Chinese Acad Sci, Res Ctr Ecoenvironm Sci, State Key Lab Environm Chem & Ecotoxicol, Beijing 100085, Peoples R China
3.Jianghan Univ, Inst Environm & Hlth, Wuhan 430056, Hubei, Peoples R China
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GB/T 7714
Liu, Aifeng,Zhao, Zongshan,Qu, Guangbo,et al. Transformation/degradation of tetrabromobisphenol A and its derivatives: A review of the metabolism and metabolites[J]. ENVIRONMENTAL POLLUTION,2018,243:1141-1153.
APA Liu, Aifeng,Zhao, Zongshan,Qu, Guangbo,Shen, Zhaoshuang,Shi, Jianbo,&Jiang, Guibin.(2018).Transformation/degradation of tetrabromobisphenol A and its derivatives: A review of the metabolism and metabolites.ENVIRONMENTAL POLLUTION,243,1141-1153.
MLA Liu, Aifeng,et al."Transformation/degradation of tetrabromobisphenol A and its derivatives: A review of the metabolism and metabolites".ENVIRONMENTAL POLLUTION 243(2018):1141-1153.
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