QIBEBT-IR
Synthesis and Electronic Structure of Boron-Graphdiyne with an sp-Hybridized Carbon Skeleton and Its Application in Sodium Storage
Wang, Ning1; Li, Xiaodong1,2; Tu, Zeyi2,3; Zhao, Fuhua1; He, Jianjiang1; Guan, Zhaoyong1; Huang, Changshui1; Yi, Yuanping3; Li, Yuliang3
2018-04-03
Source PublicationANGEWANDTE CHEMIE-INTERNATIONAL EDITION
ISSN1433-7851
Volume57Issue:15Pages:3968-3973
AbstractBoron-graphdiyne (BGDY), which has a unique pi-conjugated structure comprising an sp-hybridized carbon skeleton and evenlydistributed boron heteroatoms in a well-organized 2D molecular plane, is prepared through a bottom-up synthetic strategy. Excellent conductivity, a relatively low band gap and a packing mode of the planar BGDY are observed. Notably, the unusual bonding environment of the all sp-carbon framework and the electron-deficient boron centers generates affinity to metal atoms, and thus provides extra binding sites. Furthermore, the expanded molecule pores of the BGDY molecular plane can also facilitate the transfer of metal ions in the perpendicular direction. The practical effect of the all sp-carbon structure and boron heteroatoms on the properties of BGDY are demonstrated in its performance as the anode in sodium-ion batteries.
SubtypeArticle
KeywordBoron Carbon Materials Electrochemistry Energy Storage Graphdiyne
WOS HeadingsScience & Technology ; Physical Sciences
DOI10.1002/anie.201800453
WOS KeywordNANOTUBES ; CARBYNE
Indexed BySCI
Language英语
WOS Research AreaChemistry
Funding OrganizationNational Natural Science Foundation of China(21790050 ; Hundred Talents Program, Frontier Science Research Project(QYZDB-SSW-JSC052) ; Strategic Priority Research Program of the Chinese Academy of Sciences(XDB12020200) ; Natural Science Foundation of Shandong Province (China) for Distinguished Young Scholars(JQ201610) ; 21790051 ; 21771187)
WOS SubjectChemistry, Multidisciplinary
WOS IDWOS:000428350200017
PublisherWILEY-V C H VERLAG GMBH
Citation statistics
Cited Times:31[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.qibebt.ac.cn/handle/337004/10804
Collection中国科学院青岛生物能源与过程研究所
Corresponding AuthorHuang, Changshui; Li, Yuliang
Affiliation1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, 189 Songling Rd, Qingdao 266101, Peoples R China
2.Univ Chinese Acad Sci, 19A Yuquan Rd, Beijing 100049, Peoples R China
3.Chinese Acad Sci, CAS Key Lab Organ Solids, BNLMS, Inst Chem, Beijing 100190, Peoples R China
Recommended Citation
GB/T 7714
Wang, Ning,Li, Xiaodong,Tu, Zeyi,et al. Synthesis and Electronic Structure of Boron-Graphdiyne with an sp-Hybridized Carbon Skeleton and Its Application in Sodium Storage[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2018,57(15):3968-3973.
APA Wang, Ning.,Li, Xiaodong.,Tu, Zeyi.,Zhao, Fuhua.,He, Jianjiang.,...&Li, Yuliang.(2018).Synthesis and Electronic Structure of Boron-Graphdiyne with an sp-Hybridized Carbon Skeleton and Its Application in Sodium Storage.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,57(15),3968-3973.
MLA Wang, Ning,et al."Synthesis and Electronic Structure of Boron-Graphdiyne with an sp-Hybridized Carbon Skeleton and Its Application in Sodium Storage".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 57.15(2018):3968-3973.
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