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Ultrasensitive sensor based on nano-Cu/polyaniline/nickel foam for monitoring H2O2 in exhaled breath
Liu, Aifeng1; Liang, Jing1; Shi, Rongguang2; Zhao, Zongshan1; Tian, Yong1
2018-07-01
发表期刊JOURNAL OF BREATH RESEARCH
ISSN1752-7155
卷号12期号:3
摘要A sensitive, rapid and easy operated sensor for hydrogen peroxide (H2O2) determination in exhaled breath was developed in this study. The polyaniline (PANI) film and Cu nanoparticles (NPs) were successively electrochemical deposited on the surface of the three-dimensional nickel foam (NF), i.e., synthetized nano-Cu/polyaniline/NF. The Ni foam facilitates the charge and mass transfer, and it also provides a large amount of anchoring sites for CuNP deposition. The synergistic electro-catalytic actions between Cu NPs and PANI highly enhanced the reduction current of H2O2. Under the optimized conditions, the linear range for monitoring H2O2 extends from 0.01 to 500 nM (R-2 = 0.998), and the limit of detection is 0.0026 nM. Integrating with collection of exhaled breath in a fritted midget bubbler, the developed sensor can clearly identify the difference of H2O2 levels between the smokers and non-smokers, as well as before and after smoking for these subjects. Its application performance indicates the developed sensor possesses a great potential for routine analysis of H2O2 in exhaled breath.
文章类型Article
关键词Cu Nanoparticle Nickel Foam Polyaniline Hydrogen Peroxide Exhaled Breath
WOS标题词Science & Technology ; Life Sciences & Biomedicine
DOI10.1088/1752-7163/aaa672
关键词[WOS]GLASSY-CARBON ELECTRODE ; HYDROGEN-PEROXIDE ; OXIDE ; CONDENSATE ; ASTHMA ; NANOCOMPOSITE ; BIOSENSOR ; CIGARETTE ; COPD ; FILM
收录类别SCI
语种英语
WOS研究方向Biochemistry & Molecular Biology ; Respiratory System
项目资助者National Natural Science Foundation of China(21707148 ; Qingdao Scientific and Technological Program(15-9-2-123-ns) ; Primary Research & Development Plan of Shandong Province(2016GSF117039) ; 21607161)
WOS类目Biochemical Research Methods ; Respiratory System
WOS记录号WOS:000427083000001
出版者IOP PUBLISHING LTD
引用统计
文献类型期刊论文
条目标识符http://ir.qibebt.ac.cn/handle/337004/10670
专题绿色化学催化研究组
通讯作者Zhao, Zongshan
作者单位1.Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, CAS Key Lab Biobased Mat, Qingdao 266101, Peoples R China
2.Minist Agr, Agroenvironm Protect Inst, Tianjin 300191, Peoples R China
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GB/T 7714
Liu, Aifeng,Liang, Jing,Shi, Rongguang,et al. Ultrasensitive sensor based on nano-Cu/polyaniline/nickel foam for monitoring H2O2 in exhaled breath[J]. JOURNAL OF BREATH RESEARCH,2018,12(3).
APA Liu, Aifeng,Liang, Jing,Shi, Rongguang,Zhao, Zongshan,&Tian, Yong.(2018).Ultrasensitive sensor based on nano-Cu/polyaniline/nickel foam for monitoring H2O2 in exhaled breath.JOURNAL OF BREATH RESEARCH,12(3).
MLA Liu, Aifeng,et al."Ultrasensitive sensor based on nano-Cu/polyaniline/nickel foam for monitoring H2O2 in exhaled breath".JOURNAL OF BREATH RESEARCH 12.3(2018).
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