| Investigation on three new metal carboxydiphosphonates: Syntheses, structures, magnetic and luminescent properties | |
| Tang, Si-Fu; Pan, Xiao-Bo; Lv, Xiao-Xia; Zhao, Xue-Bo | |
| 2013 | |
| 发表期刊 | JOURNAL OF SOLID STATE CHEMISTRY
 |
| 卷号 | 197期号:6页码:139-146 |
| 摘要 | A new multifunctionalized phosphoric acid, (2-(diphosphonomethylamino)nicotinic acid, Py(COOH)(NHCH-(PO3H2)(2)), H5L1), has been employed as ligand for the construction of new metal phosphonates. By reacting it with different metal chlorides under hydrothermal condition, three new transition metal phosphonates, namely, [Co-2(HL1)(H2O)(5)H2O](3) (1), Zn(H3L1) (2) and [Cd(H3L1)(H2O)(2)][H2O] (3) were successfully obtained. The single-crystal structure measurements indicated that the coordination mode of ligand H5L1 is metal-dependant and results in different structures. For compound 1, it features 2D layered structure. Whereas compounds 2 and 3 have 1D chain structures. Under the excitation of 250 nm light, both compounds 2 and 3 show intraligand and ligand to metal charge transfer (LMCT) emission bands at about 415 and 420 nm, respectively. Magnetic study shows that compound 1 displays antiferromagnetic behavior. (C) 2012 Elsevier Inc. All rights reserved. |
| 文章类型 | Article |
| 关键词 | Metal Phosphonates Crystal Structure Luminescence Magnetism |
| 学科领域 | 储氢及新型纳孔材料 |
| WOS标题词 | Science & Technology ; Physical Sciences |
| DOI | 10.1016/j.jssc.2012.08.052 |
| 关键词[WOS] | LAYERED CADMIUM PHOSPHONATE ; RAY-POWDER STRUCTURES ; COORDINATION POLYMERS ; CRYSTAL-STRUCTURES ; CARBOXYLATE-PHOSPHONATES ; BUILDING-BLOCKS ; LIGANDS ; DIPHOSPHONATES ; FRAMEWORKS ; CD(II) |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS研究方向 | Chemistry |
| WOS类目 | Chemistry, Inorganic & Nuclear ; Chemistry, Physical |
| WOS记录号 | WOS:000312281000019 |
| 引用统计 | |
| 文献类型 | 期刊论文 |
| 条目标识符 | http://ir.qibebt.ac.cn/handle/337004/1058 |
| 专题 | 储氢及新型纳孔材料团队（过去） |
| 作者单位 | Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol, Qingdao 266101, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tang, Si-Fu,Pan, Xiao-Bo,Lv, Xiao-Xia,et al. Investigation on three new metal carboxydiphosphonates: Syntheses, structures, magnetic and luminescent properties[J]. JOURNAL OF SOLID STATE CHEMISTRY,2013,197(6):139-146. |
| APA | Tang, Si-Fu,Pan, Xiao-Bo,Lv, Xiao-Xia,&Zhao, Xue-Bo.(2013).Investigation on three new metal carboxydiphosphonates: Syntheses, structures, magnetic and luminescent properties.JOURNAL OF SOLID STATE CHEMISTRY,197(6),139-146. |
| MLA | Tang, Si-Fu,et al."Investigation on three new metal carboxydiphosphonates: Syntheses, structures, magnetic and luminescent properties".JOURNAL OF SOLID STATE CHEMISTRY 197.6(2013):139-146. |
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